dc.creator Albert, S. en_US dc.creator Winnewisser, B. P. en_US dc.creator Winnewisser, M. en_US dc.date.accessioned 2007-11-20T17:15:33Z dc.date.available 2007-11-20T17:15:33Z dc.date.issued 1995 en_US dc.identifier 1995-FA'-06 en_US dc.identifier.uri http://hdl.handle.net/1811/29896 dc.description Author Institution: Justus-Liebig-Universität Giessen, 35392 Giessen, Germany. en_US dc.description.abstract Fulminic acid belongs to the class of quasilinear molecules. Precise ab initio methods are not available to reproduce the quasilinear behavior of the molecule. In particular, the calculations cannot predict the multitude of accidental resonance interactions. We have now analyzed the infrared spectra of HCNO and its isotopomers $H^{13}CNO$ and $H^{13}C^{15}NO$ up to $7000 cm^{-1}$. More then 30000 lines could be assigned. The low symmetry of the molecule and the anharmonic quasilinear bending mode lead to an extraordinarily rich array of interactions. Most of the interactions could be classified into a network of resonance systems. As a result of such classifications, it has been possible to identify dark states. An overview and comparison of the different network in HCNO, $H^{13}CNO$ and $H^{13}C^{15}NO$ will be discussed. The term value schemes built up with the help of the Ritz combination principle will be presented. en_US dc.format.extent 51311 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title OVERVIEW OF THE NETWORKS OF RESONANCE SYSTEMS IN THE SPECTRA OF FULMINIC ACID AND ITS ISOTOPOMERS en_US dc.type article en_US
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