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dc.creatorOesterling, L. C.en_US
dc.creatorFerguson, D. W.en_US
dc.creatorHerbst, E.en_US
dc.creatorDe Lucia, Frank C.en_US
dc.date.accessioned2007-11-20T17:14:52Z
dc.date.available2007-11-20T17:14:52Z
dc.date.issued1995en_US
dc.identifier1995-TK-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/29869
dc.descriptionAuthor Institution: The Ohio State University, 174 West 18th Avenue, Columbus, OH 43210.en_US
dc.description.abstractAlthough deuterated isotopomers of organic molecules have been detected in various interstellar sources, singly deuterated isotopomers have not yet been detected in the interstellar medium due to a lack of laboratory spectroscopic data. To aid in the study of interstellar spectra, the analysis of the rotational-torsional spectrum of deuterated $methy^{l}$ formate has been extended into the millimeter-wave and submillimeter-wave regions of the electromagnetic spectrum. The A (symmetric) and E (asymmetric) torsional substates of the ground $(\nu_{t} = 0)$ torsional state of deuterated methyl formate have been fit to a rms deviation of 85 kHz using a direct digonalization procedure of an extended global internal -axis method (IAM) Hamiltonian. Using this global IAM approach, the A and E states of the ground torsional state for methyl formate have been reanalyzed and a rms deviation of less than 100 kHz has been obtained for the global fit of our data.en_US
dc.format.extent53011 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE MILLIMETER - AND SUBMILLIMETER - WAVE SPECTRUM OF METHYL FORMATE $(HCOOCH_{3})$ AND SYMMETRIC MONODEUTERATED METHYL FORMATE $(DCOOCH_{3})$en_US
dc.typearticleen_US


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