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dc.creatorNakajima, A.en_US
dc.creatorHirano, M.en_US
dc.creatorHasumi, R.en_US
dc.creatorKaya, K.en_US
dc.creatorCarter, Christopher C.en_US
dc.creatorWilliamson, James M.en_US
dc.creatorMiller, Terry A.en_US
dc.date.accessioned2007-11-20T17:14:09Z
dc.date.available2007-11-20T17:14:09Z
dc.date.issued1995en_US
dc.identifier1995-TH-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/29821
dc.description1. S. Tanabe, T. Ebata, M. Fujii, and N. Mikami, Chem. Phys. Lett. 215. 347 (1993).en_US
dc.descriptionAuthor Institution: Keio University, 3-14-I Hiyoshi, Kohoku-ku, Yokohama 223, JAPAN.; "Laser Spectroscopy Facility, The Ohio State University", Columbus, Ohio 43210.en_US
dc.description.abstractThe geometric structures of 7-azaindole (7-AzI), its dimer, and $7-AzI-H_{2}O$ complexes were investigated by laserinduced fluorescence (LIF) with high resolution $(-0.01 cm^{-1})$. For the 7-AzI dimer, the LIF spectrum shows unresolved rotational envelope due to lifetime broadening, and the rotational contour has been analyzed to T-shaped structure. The structure obtained is consistent with the fact that the dimer shows no proton-transfer reaction. For the $7-AzI-(H_{2}O)_{n}$ complexes (n=1-3), the LIF spectra show partially resolved rotational structure, which has been analyzed. This analysis yields the rotational constants and the structure; the $H_{2}O$ molecule is located in the molecular plane, forming a hydrogen bond with both N and H(-N) atoms. The structure is similar to that of phenol-water complex, where the interaction through hydrogen bonds plays an important role in the complex $formation^{1}$. A preliminary analysis for $7-AzI-(H_{2}O)_{2}$ and $-(H_{2}O)_{3}$, furthermore, shows that the second and third $H_{2}O$ are located in the molecular plane of 7-AzI, forming a network of hydrogen bonds.en_US
dc.format.extent69836 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSPECTROSCOPIC STUDY OF 7-AZAINDOLE MOLECULE AND ITS COMPLEXESen_US
dc.typearticleen_US


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