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dc.creatorHan, Dongshengen_US
dc.creatorRittby, C. M. L.en_US
dc.creatorGraham, W. R. M.en_US
dc.date.accessioned2007-11-20T17:12:35Z
dc.date.available2007-11-20T17:12:35Z
dc.date.issued1995en_US
dc.identifier1995-TC-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/29766
dc.description1. C.M.L. Rittby, results of unpublished CCSD calculation.en_US
dc.descriptionAuthor Institution: Texas Christian University, Fort Worth, TX 76129.en_US
dc.description.abstractThe vibrational fundamentals of the $SiC_{2}H$ molecule have been observed for the first time, by trapping the products of the vacuum ultraviolet photolysis of silane and acetylene in an Ar matrix at 10 K. Isotopic shifts for deuterium and carbon-13 have been obtained to support the identification of the $\nu_{2} (\sigma)$ carbon-carbon stretching vibration at $1998.8 cm^{-1}$. The observed frequencies of vibrational fundamentals and isotopic shifts are in good agreement with ab initio $calculations.^{1}$ A full analysis of vibrational fundamentals will be presented.en_US
dc.format.extent39901 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleFOURIER TRANSFORM INFRARED DETECTION AND ISOTOPIC STUDY OF THE $SiC_{2}H$ MOLECULE IN AN Ar MATRIX AT 10Ken_US
dc.typearticleen_US


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