Show simple item record

dc.creatorBunker, P. R.en_US
dc.creatorKolbuszewski, M.en_US
dc.creatorJensen, Peren_US
dc.creatorBrumm, Martinen_US
dc.creatorAnderson, M. A.en_US
dc.creatorBarclay, W. L., Jr.en_US
dc.creatorZiurys, L. M.en_US
dc.creatorNi, Yongen_US
dc.creatorHarris, David O.en_US
dc.date.accessioned2007-11-20T17:10:35Z
dc.date.available2007-11-20T17:10:35Z
dc.date.issued1995en_US
dc.identifier1995-RJ-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/29694
dc.description$^{1}$ P. Jensen, J. Mol. Spectrosc. 128, 478-501 (1988); J. Chem. Soc. Faraday Trans. 2 84, 1315-1340 (1988); in: ""Methods in Computational Molecular Physics'' (S. Wilson and G.H.F. Diercksen, Eds.), Plenum, New York, 1992.en_US
dc.descriptionAuthor Institution: National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6; Bergische Universität, Gesamthochschule Wuppertal, D-42097 Wuppertal, Germany.; Arizona State University, Tempe, AZ 85287-1604, U.S.A.; The University of California, Santa Barbara, CA 93106, U.S.A.en_US
dc.description.abstractUsing millimeter wave absorption spectroscopy we have recorded pure rotation spectra of MgOH for the ground vibrational state and for six excited vibrational states. We have also determined a large number of bending vibrational energies, and the MgO stretching frequency, using dispersed fluorescence studies of both MgOH and MgOD. By a weighted least squares optimized fitting to this data using the variational approach $MORBID^{1}$ Morse Oscillator Rigid Bender Internal Dynamics), with a basis set of Morse oscillator stretching functions and rigid bender functions, we have derived the full ground state potential surface in an analytical form. Although the equilibrium structure is determined to be linear, the bending part of the potential is rather flat and symptoms of quasilinearity are present; for example in the $\nu_{2} = 2$ state the l = 2 component is below the l = 0 component.en_US
dc.format.extent75682 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleNEW ROVIBRATIONAL DATA FOR MgOH AND MgOD, AND THE INTERNUCLEAR POTENTIAL FUNCTION OF THE GROUND ELECTRONIC STATEen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record