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dc.creatorNesselrodt, Dale R.en_US
dc.creatorPotts, Alan R.en_US
dc.creatorBaer, Tomasen_US
dc.date.accessioned2007-11-20T17:08:59Z
dc.date.available2007-11-20T17:08:59Z
dc.date.issued1995en_US
dc.identifier1995-RF-09en_US
dc.identifier.urihttp://hdl.handle.net/1811/29640
dc.descriptionAuthor Institution: University of North Carolina, Chapel Hill, NC 27599-3290en_US
dc.description.abstractThe various rotamer conformations associated with the hindered ethyl group rotor in ethyl substituted cyclohexanones and cyclopentanones have been trapped in a supersonic expansion and spectroscopically analyzed by 2 + 1 resonance enhanced multiphoton ionization (REMPI) via the $3s \leftarrow n$ Rydberg transition. The rapid cooling in the supersonic expansion effectively freezes many of the conformations at their room temperature equilibrium concentrations. The various rotamers, including some in the axial orientation, were identified by comparing peak intensities with those calculated by both molecular mechanics (MMX) and ab initio MO methods. Excellent agreement between the calculations and the experimental results is noted.en_US
dc.format.extent42991 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleOBSERVATION OF ETHYL SUBSTITUTED CYCLOHEXANONE AND CYCLOPENTANONE ROTAMERS USING RESONANCE ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPYen_US
dc.typearticleen_US


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