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dc.creatorHowe, J. D.en_US
dc.creatorJohnson, Russell D., IIIen_US
dc.creatorHudgens, J. W.en_US
dc.creatorIrikura, K. K.en_US
dc.creatorAshfold, Mike N. R.en_US
dc.date.accessioned2007-11-20T17:08:53Z
dc.date.available2007-11-20T17:08:53Z
dc.date.issued1995en_US
dc.identifier1995-RF-06en_US
dc.identifier.urihttp://hdl.handle.net/1811/29637
dc.descriptionAuthor Institution: University of Bristol, Bristol BS8 1TS, United Kingdom.; National Institute of Standards and Technology, Gaithersburg, MD 20899.en_US
dc.description.abstractNine new electronic states of $PF_{2}$ have been observed using Resonance Enhanced Multiphoton Ionization Spectroscopy (REMPI). The states are observed in the $50000 to 71000 cm^{-1}$ energy region by 2+1 REMPI. The similarity of the excited state vibrational frequencies to the vibrational frequencies of the ground state ion indicate the Rydberg nature of the excited states. Ab inito calculations have been performed on the ground states of the neutral and ion to determine vibrational frequencies and the ionization potential at the QCISD(T)/6-311+G(3df) level. The energies of the lowest excited states of each symmetry were obtained at the CASPT2(3,8)/ANO level. These predominantly valence states all reside below $50000 cm^{-1}$.en_US
dc.format.extent66602 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINVESTIGATION OF $PF_{2}$ BY REMPI SPECTROSCOPY AND AB INITIO CALCULATIONS.en_US
dc.typearticleen_US


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