AB INITIO CALCULATION OF ROVIBRONIC TRANSITION SPECTRA OF CaH

Abstract

The ground $(1^{2}\Sigma^{+}, X)$ and excited electronic states, $1^{2}\Pi (A), 2^{2}\sigma^{+} (B, B^{\prime}), 1^{2}\Delta, 2^{2}\Pi (E), 3^{2}\Sigma^{+}(D), 4^{2}\Sigma^{+} (C), 5^{2}\Sigma^{+} (K), 3^{2}\Pi (L)$ and $2^{2}\Delta$, of CaH are calculated by extensive ab initio configuration interactions. Calculated spectroscopic constants, in particular, the excitation energies $(T_{e})$ are more accurate than previous calculations and agree well with the currently available experimental data. This work confirms the single vibrational level $v^{\prime} = 4$ bound to the second well of the B state calculated from the experimental data by Martin (J. Chem. Phys. 88 (1988) 1797-1806). Calculated oscillator strengths for the B-X and D-X show irregular band structures because of multiple avoided crossings of the potential energy curves. The avoided crossing between the D and C state should be taken into account to explain the apparent pertubations observed in the experimental spectra. The wave functions, dipole moments and transition dipole moments of these states are discussed in detail.