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dc.creatorKukolich, Stephen G.en_US
dc.creatorMcKay, R. T.en_US
dc.creatorBreckenridge, S. M.en_US
dc.creatorFlores, L. D.en_US
dc.creatorMorris, G. E.en_US
dc.creatorSickafoose, S. M.en_US
dc.creatorMorrison, D. L.en_US
dc.date.accessioned2007-11-20T17:06:45Z
dc.date.available2007-11-20T17:06:45Z
dc.date.issued1995en_US
dc.identifier1995-ML-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/29563
dc.descriptionAuthor Institution: The University of Arizona, Tucson, AZ 85721en_US
dc.description.abstractThe transition metal complex $C_{5}H_{5}Cr(CO)_{2}NO$ is a relatively simple, "piano-stool" type complex which provides the opportunity to compare nitrosyl and carbonyl ligand binding. The nitrosyl and carbonyl ligands form significantly different angles with the $C_{5}H_{5}-Cr$ axis, and this results in a near-symmetric-top inertia tensor for the common isotopomer. For the normal isotopomer, A = 1001.693(2), B = 797.2724(6) and C = 797.0143(6) MHz. The $C_{5}H_{5} - Cr - NO$ angle is $126.9(5)^{\circ}$ and the $C_{5}H_{5}-Cr-CO$ angle is $120.1(2)^{\circ}$. The distance from the Cr atom to the $C_{5}H_{5}$ ring is $z (Cr -C_{5}H_{5}) = 1.88(1) {\AA}$. Other structural parameters are obtained and discussed. The $C_{5}H_{5}$ ring is oriented so that two of the cyclopentadienyl carbon atoms are staggered with respect to the NO nitrogen atom. The $^{14}N$ quadrupole coupling values are $eQq_{aa} = 0.312(2)$ and $eQq_{bb} = -0.448(2)$ MHz.en_US
dc.format.extent53071 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMICROWAVE SPECTRUM AND STRUCTURE FOR CYCLOPENTADIENYL CHROMIUM DICARBONYL NITROSYLen_US
dc.typearticleen_US


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