dc.creator Sylvestre, Jeffrey J. en_US dc.creator Le Roy, Robert J. en_US dc.date.accessioned 2007-11-20T17:06:40Z dc.date.available 2007-11-20T17:06:40Z dc.date.issued 1995 en_US dc.identifier 1995-MK-01 en_US dc.identifier.uri http://hdl.handle.net/1811/29539 dc.description Author Institution: University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. en_US dc.description.abstract When a chromophore is trapped inside a rare gas matrix, its characteristic vibrational frequencies are displaced from those of the free molecule. The resulting shifted infrared spectrum depends on both the temperature and the nature of the vacancy site occupied by the chromophore. Combining Monte-Carlo averaging techniques with both a realistic model for the chromophore-matrix interaction and a means of estimating the frequency shifts allows us to examine the effect of temperature and the size and shape of the trapping site on the predicted spectrum. This paper describes the application of this approach to the case of $SF_{6}$ in an Ar matrix. en_US dc.format.extent 35825 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title MONTE CARLO SIMULATION OF CHROMOPHORE FREQUENCY SHIFTS IN RARE GAS MATRICES en_US dc.type article en_US
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