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dc.creatorSylvestre, Jeffrey J.en_US
dc.creatorLe Roy, Robert J.en_US
dc.date.accessioned2007-11-20T17:06:40Z
dc.date.available2007-11-20T17:06:40Z
dc.date.issued1995en_US
dc.identifier1995-MK-01en_US
dc.identifier.urihttp://hdl.handle.net/1811/29539
dc.descriptionAuthor Institution: University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.en_US
dc.description.abstractWhen a chromophore is trapped inside a rare gas matrix, its characteristic vibrational frequencies are displaced from those of the free molecule. The resulting shifted infrared spectrum depends on both the temperature and the nature of the vacancy site occupied by the chromophore. Combining Monte-Carlo averaging techniques with both a realistic model for the chromophore-matrix interaction and a means of estimating the frequency shifts allows us to examine the effect of temperature and the size and shape of the trapping site on the predicted spectrum. This paper describes the application of this approach to the case of $SF_{6}$ in an Ar matrix.en_US
dc.format.extent35825 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMONTE CARLO SIMULATION OF CHROMOPHORE FREQUENCY SHIFTS IN RARE GAS MATRICESen_US
dc.typearticleen_US


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