THE VIBRATIONAL AND ROVIBRATIONAL ENERGY PATTERN IN ${^{12}}C_{2}H_{2}$ M. ABBOUTI TEMSAMANI

dc.creator	Herman, M.	en_US
dc.creator	Jost, R.	en_US
dc.date.accessioned	2007-11-20T17:06:06Z
dc.date.available	2007-11-20T17:06:06Z
dc.date.issued	1995	en_US
dc.identifier	1995-MI-12	en_US
dc.identifier.uri	http://hdl.handle.net/1811/29523
dc.description	I. M. Abbouti Temsamani and M. Herman, J. Chem. Phys., in press	en_US
dc.description	Author Institution: Université Libre de Bruxelles, Roosevelt ave., 50, B-1050, Brussels, Belgium.; Laboratoire des Champs Magnétiques Intenses, BP166x, 38042 Grenoble, France.	en_US
dc.description.abstract	We have build an Hamiltonian which quantitatively reproduces the vibrational energy levels in ${^{12}}C_{2}H_{2}$, up to the near-infrared, and possibly visible $ranges^{1}$. It is based on the clustering of the vibrational levels induced by a defined set of anharmonic resonances, which allows to block-diagonalize the energy matrix. We have now inserted the terms adequate for predicting the rotational structure in each cluster, allowing to reproduce the anomalous distortion constants determined in various overtone and combination bands. In addition, the mean energy spacing between the vibrational levels has been studied within selected clusters for various J-values.	en_US
dc.format.extent	44371 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	THE VIBRATIONAL AND ROVIBRATIONAL ENERGY PATTERN IN ${^{12}}C_{2}H_{2}$ M. ABBOUTI TEMSAMANI	en_US
dc.type	article	en_US