Show simple item record

dc.creatorOgilvie, J. F.en_US
dc.date.accessioned2007-11-20T17:05:49Z
dc.date.available2007-11-20T17:05:49Z
dc.date.issued1995en_US
dc.identifier1995-MI-02en_US
dc.identifier.urihttp://hdl.handle.net/1811/29513
dc.descriptionAuthor Institution: Institute of Atomic Molecular Sciences, P. O. Box 23-166, Taipei 10764, Taiwanen_US
dc.description.abstractFrom analyses of vibration-rotational spectra of diatomic and linear triatomic molecules, particularly LiH, we evaluated the term coefficients $Y_{kl}$ and various $Z_{kl}$ in terms of mechanical (related to vibration and rotation of the nuclei about the centre of mass), adiabatic, and nonadiabatic vibrational and rotationl effects (as the associated electrons follow imperfectly the nuclei). We propose generalisations about relative orders of magnitudes of mechanical, adiabatic and nonadiabatic effects that pertain to intramolecular dynamics of free small molecules, and discuss the importance of taking into account all these effects in either comparing results deduced from experiment with those drawn from computations of molecular electronic structure or deducing structural information from spectral parameters. Various approaches to the reduction of spectral data of diatomic molecules are compared, and the chemical and physical significance of the results is discussed.en_US
dc.format.extent61097 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleADIABATIC AND NONADIABATIC EFFECTS IN MOLECULAR SPECTRA OF DIATOMIC MOLECULES; 2 PURE ROTATIONAL AND VIBRATION-ROTATIONAL DATA OF LiH AS A TEST CASEen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record