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dc.creatorVituccio, David T.en_US
dc.creatorHerrmann, R. F. W.en_US
dc.creatorGolonzka, Olegen_US
dc.creatorErnst, Wolfgang E.en_US
dc.date.accessioned2007-11-20T17:04:41Z
dc.date.available2007-11-20T17:04:41Z
dc.date.issued1995en_US
dc.identifier1995-FF-05en_US
dc.identifier.urihttp://hdl.handle.net/1811/29474
dc.description1. E. C. Honea, M. L. Homer, P. Labastie, and R.L. Whetten, Phys. Rev. Lett. 63, 394 (1989). 2. P. D. Dao, K. I. Peterson, and A. W. Castleman Jr., J. Chem. Phys. 80, 563 (1984).en_US
dc.descriptionAuthor Institution: The Pennsylvania state University, 104 Davey Lab., University Park, PA 16802.; Max-Born-Institut, Rudower Chaussee 6, D-12489 Berlin, Germany.en_US
dc.description.abstractOxides and flurides of alkali clusters were produced by reacting a beam of metal clusters with $N_{2}O$ or $SF_{6}$ in the region between nozzle and skimmer. The threshold for single photon ionization was measured by using a pulsed frequency doubled visible dye laser or a UV dye laser and detecting ions with a quadrupole mass spectrometer. Resonant two photon ionization and depletion spectroscopy were employed to record optical spectra. Unfortunately, the exothermic reaction yields rather warm clusters and no vibrational structure was resolved. While our measured photoionization threshold $I_{p} = 3.81 (5) eV$ for $Na_{2}F$ is in good agreement with former $experiments^{1}$ we determined $I_{p} = 3.57 (5) eV$ for $Na_{3}O$ which is significantly lower than the previously published value of $3.90 (15) eV.^{2}$en_US
dc.format.extent61538 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titlePHOTOIONIZATION AND OPTICAL ABSORPTION OF $Na_{2}F$ AND $Na_{3}O$,en_US
dc.typearticleen_US


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