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dc.creatorKukolich, Stephen G.en_US
dc.date.accessioned2007-08-31T14:12:47Z
dc.date.available2007-08-31T14:12:47Z
dc.date.issued1982en_US
dc.identifier1982-RB-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/29207
dc.description$^{1}$T.J. Balle, E.J. Camphell, M.R. Keenan and W.H. Flygare, J. Chem. Phys. 71, 2723 (1979); 72, 922 (1980) $^{2}$T.J. Balle and W.H. Flygare, Rev. Sci. instrum. 52, 33 (1981)en_US
dc.description.abstractThe Fourier transform - pulsed beam microwave $spectrometer^{1, 2}$ developed by W.H. Flygare, T.J. Balle and coworkers allows high resolution measurements of rotational transitions on molecules which are difficult or impossible to measure using standard techniques. Previous measurements have been made on both $NONO_{2}$ and $PH_{2}D$, but at much lower resolution. Far $NONO_{2}$ hyperfine structure due to both nitrogen atoms was completely resolved and quadrupole coupling tensors were obtained. The values obtained differ significantly from those obtained for the free molecules NO and $NO_{2}$. Splitting of the rotational transitions in $PH_{2}D$ was observed due to the $^{31}P$ spin-rotation interaction and $^{1}H$ spin-rotation interaction. Deuterium quadrupole coupling and inversion splitting were not resolved. The upper limit on the Inversion splitting from these measurements is 20 KHz.en_US
dc.format.extent81202 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMEASUREMENTS OF HYPERFINE STRUCTURE IN $NONO_{2}$ AND $PH_{2}$D USING THE FLYGARE-BALLE PULSED BEAM SPECTROMETERen_US
dc.typearticleen_US


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