RYDBREG STATES OF ${Li_{2}}$ AND MOLECULAR CONSTANTS OF ${Li_{2}}^{+}$
dc.creator | Bernheim, R. A. | en_US |
dc.creator | Gold, L. P. | en_US |
dc.creator | Tipton, T. | en_US |
dc.date.accessioned | 2007-08-31T14:12:16Z | |
dc.date.available | 2007-08-31T14:12:16Z | |
dc.date.issued | 1982 | en_US |
dc.identifier | 1982-MG-5 | en_US |
dc.identifier.uri | http://hdl.handle.net/1811/29187 | |
dc.description | $^{1}$ D.D. Konowalow and M.E. Rosenkrantz, Chem. Phys. Letters 61, 489 (1979). | en_US |
dc.description.abstract | Thirty-one new excited gerade states of $^{7}Li_{2}$ have been characterized by means of pulsed optical-optical double resonance spectroscopy. Twenty-nine of these have been identified as the lowest members of three Rydberg series: $3-15d\pi^{1}\Pi_{g}, 3-10d\sigma^{1}{\Sigma^{+}}_{g}$, and $3-10s\sigma^{1}{\Sigma_{g}}^{+}$, A fit of a Rydberg formula to the $^{1}{\Pi^{-}}_{g}$ term energies yield a value of $41496\pm 4 cm^{-1}$ for the ionization potential of $Li_{2}$. Extrapolations of the vibrational frequencies, rotational constants, and dissociation energies of these states give estimates for the corresponding quantities for the ground state of ${Li_{2}}^{+}$ which are in good agreement with those obtained by ab initio $calculations^{1}$. | en_US |
dc.format.extent | 69218 bytes | |
dc.format.mimetype | image/jpeg | |
dc.language.iso | English | en_US |
dc.publisher | Ohio State University | en_US |
dc.title | RYDBREG STATES OF ${Li_{2}}$ AND MOLECULAR CONSTANTS OF ${Li_{2}}^{+}$ | en_US |
dc.type | article | en_US |
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