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dc.creatorPolavarapu, P. L.en_US
dc.date.accessioned2007-08-31T14:11:47Z
dc.date.available2007-08-31T14:11:47Z
dc.date.issued1982en_US
dc.identifier1982-MF-2en_US
dc.identifier.urihttp://hdl.handle.net/1811/29169
dc.description.abstractIn the electric field perturbative calculations of Raman intensities, molecular orbital schemes first evaluate the polarizability derivatives in Cartesian space and then transform to normal coordinate space. The former, $\partial\alpha/{\partial\chi}_\Lambda$, where $\alpha$ is molecular polarizability derivative tensor and $\chi_\Lambda$ represents cartesian displacement coordinates of atom A, are referred to as atomic Raman tensors and relate to the sum of (3N-6) Raman intensities through an extremely simple and convenient expression. This sum rule can be used to calculate the atomic Raman tensor parameters, such as anisotropy of $\partial\alpha/{\partial\chi}_\Lambda$. These atomic Raman tensor parameters and the sum rule can in turn be used to predict the Raman intensity sums for isotopic analogues and for closely related molecules.en_US
dc.format.extent71101 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleATOMIC RAMAN TENSORS AND INTENSITY SUM RULEen_US
dc.typearticleen_US


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