dc.creator Jensen, Per en_US dc.creator Bunker, P. R. en_US dc.date.accessioned 2007-08-31T14:10:14Z dc.date.available 2007-08-31T14:10:14Z dc.date.issued 1982 en_US dc.identifier 1982-FA-13 en_US dc.identifier.uri http://hdl.handle.net/1811/29110 dc.description $^{1}$L. Halonen, I.M. Mills, and J. Kauppinen, Mol. Phys. 43, 913 (1981). $^{2}$P.R. Bunker, J. Mol. Spectrose. 80, 422 (1980). en_US dc.description.abstract The $\upsilon_{5}$ band manifold of $C_{3}O_{2}$ (due to the CCO bending $\upsilon_{5}$ vibration at $580.2 cm^{-1}$ combined with quanta of the CCC bending vibration $\upsilon_{7}$) observed by $Halonen et al.^{1}$ has been analyzed using a modified version of the semirigid bendor model previously described by $Bunker^{2}$. The $\upsilon_{5}$ bending mode is degenerate in the linear molecule limit and the semirigid bender Hamiltonian has been modified to account for the $\upsilon_{5}$ vibrational angular momentum around the molecules axis in the linear limit, and $\ell$-doubling effects. Several parameters have been obtained, primarily the CC bond length, the effective CCC bending potential in the $\upsilon_{5}$ state, and the $\phi_{5577}$ force constant. en_US dc.format.extent 69671 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE $\upsilon_{5}$ BAND MANIFOLD OF CARBON SUBOXIDE en_US dc.type article en_US
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