THE $\upsilon_{5}$ BAND MANIFOLD OF CARBON SUBOXIDE

dc.creator	Jensen, Per	en_US
dc.creator	Bunker, P. R.	en_US
dc.date.accessioned	2007-08-31T14:10:14Z
dc.date.available	2007-08-31T14:10:14Z
dc.date.issued	1982	en_US
dc.identifier	1982-FA-13	en_US
dc.identifier.uri	http://hdl.handle.net/1811/29110
dc.description	$^{1}$L. Halonen, I.M. Mills, and J. Kauppinen, Mol. Phys. 43, 913 (1981). $^{2}$P.R. Bunker, J. Mol. Spectrose. 80, 422 (1980).	en_US
dc.description.abstract	The $\upsilon_{5}$ band manifold of $C_{3}O_{2}$ (due to the CCO bending $\upsilon_{5}$ vibration at $580.2 cm^{-1}$ combined with quanta of the CCC bending vibration $\upsilon_{7}$) observed by $Halonen et al.^{1}$ has been analyzed using a modified version of the semirigid bendor model previously described by $Bunker^{2}$. The $\upsilon_{5}$ bending mode is degenerate in the linear molecule limit and the semirigid bender Hamiltonian has been modified to account for the $\upsilon_{5}$ vibrational angular momentum around the molecules axis in the linear limit, and $\ell$-doubling effects. Several parameters have been obtained, primarily the CC bond length, the effective CCC bending potential in the $\upsilon_{5}$ state, and the $\phi_{5577}$ force constant.	en_US
dc.format.extent	69671 bytes
dc.format.mimetype	image/jpeg
dc.language.iso	English	en_US
dc.publisher	Ohio State University	en_US
dc.title	THE $\upsilon_{5}$ BAND MANIFOLD OF CARBON SUBOXIDE	en_US
dc.type	article	en_US