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dc.creatorJensen, Peren_US
dc.creatorBunker, P. R.en_US
dc.date.accessioned2007-08-31T14:10:14Z
dc.date.available2007-08-31T14:10:14Z
dc.date.issued1982en_US
dc.identifier1982-FA-13en_US
dc.identifier.urihttp://hdl.handle.net/1811/29110
dc.description$^{1}$L. Halonen, I.M. Mills, and J. Kauppinen, Mol. Phys. 43, 913 (1981). $^{2}$P.R. Bunker, J. Mol. Spectrose. 80, 422 (1980).en_US
dc.description.abstractThe $\upsilon_{5}$ band manifold of $C_{3}O_{2}$ (due to the CCO bending $\upsilon_{5}$ vibration at $580.2 cm^{-1}$ combined with quanta of the CCC bending vibration $\upsilon_{7}$) observed by $Halonen et al.^{1}$ has been analyzed using a modified version of the semirigid bendor model previously described by $Bunker^{2}$. The $\upsilon_{5}$ bending mode is degenerate in the linear molecule limit and the semirigid bender Hamiltonian has been modified to account for the $\upsilon_{5}$ vibrational angular momentum around the molecules axis in the linear limit, and $\ell$-doubling effects. Several parameters have been obtained, primarily the CC bond length, the effective CCC bending potential in the $\upsilon_{5}$ state, and the $\phi_{5577}$ force constant.en_US
dc.format.extent69671 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE $\upsilon_{5}$ BAND MANIFOLD OF CARBON SUBOXIDEen_US
dc.typearticleen_US


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