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dc.creatorFan, H.en_US
dc.creatorIonescu, I.en_US
dc.creatorAnnesley, C.en_US
dc.creatorReid, S. A.en_US
dc.date.accessioned2006-06-15T20:52:02Z
dc.date.available2006-06-15T20:52:02Z
dc.date.issued2004en_US
dc.identifier2004-RH-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/21330
dc.descriptionAuthor Institution: Department of Chemistry, Marquette Universityen_US
dc.description.abstractWe report new measurements of the laser induced fluorescence spectra of the HCCl $A^{1}A^{\prime\prime}-X^{1}A^{1}$system in the 515-615 nm region. The spectra were obtained under jet-cooled conditions using a pulsed discharge source. The pure bending transitions $2^{n}_{0}$ with $n=5-8$ and combination bands $2^{n}_{0}3^{m}_{0}$ with $n=4-6$ and $m=1,2$ have been measured and the rotational structure fit to a asymmetric top Hamiltonian, which yielded precise values for the band origins and effective rotational constants. Consistent with previous work, only sub-bands with $K^{\prime}_{a} = 0$ appear strongly in the spectra. Fluorescence lifetimes were measured for rotational levels in each band, and the energy dependence of the lifetimes will be discussed.en_US
dc.format.extent214221 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleA LASER INDUCED FLUORESCENCE STUDY OF JET-COOLED HCCl IN THE REGION 515-615 NMen_US
dc.typearticleen_US


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