dc.creator Hepburn, J. W. en_US dc.creator Hu, Qichi en_US dc.date.accessioned 2006-06-15T20:47:12Z dc.date.available 2006-06-15T20:47:12Z dc.date.issued 2004 en_US dc.identifier 2004-MG-03 en_US dc.identifier.uri http://hdl.handle.net/1811/21191 dc.description Author Institution: University of British Columbia en_US dc.description.abstract It has already been demonstrated that the method of threshold ion-pair production spectroscopy (TIPPS) can be used to probe the energetics of molecular dissociation with spectroscopic accuracy. Since TIPPS produces a spectrum which measures energy differences between the starting neutral molecule states and the states of the ion-pair dissociation products, it can also be used to determine the spectroscopy of the ion fragments, and the dynamics of the ion-pair dissociation. The results of TIPPS experiments on the following dissociations will be used to illustrate these features of TIPPS: $H_{2}S + h\nu \rightarrow H^{+} + SH^{-} H_{2}S + h\nu \rightarrow H^{-} + SH^{+} HCN + h\nu \rightarrow H^{+} + CN^{-}$ Our results on these systems indicate that, as with neutral photodissociation, an initial state of the neutral can be coupled to a wide range of product states, meaning that the spectroscopy of highly excited ions can be studied by TIPPS. en_US dc.format.extent 242261 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title DYNAMICS OF THRESHOLD PHOTO-ION PAIR PRODUCTION IN SMALL MOLECULES en_US dc.type article en_US
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