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dc.creatorMerritt, Jeremy M.en_US
dc.creatorKüpper, Jochenen_US
dc.creatorMiller, R. E.en_US
dc.date.accessioned2006-06-15T20:44:26Z
dc.date.available2006-06-15T20:44:26Z
dc.date.issued2003en_US
dc.identifier2003-WH-01en_US
dc.identifier.urihttp://hdl.handle.net/1811/21104
dc.descriptionAuthor Institution: Department of Chemistry, The University of North Carolina at Chapel Hillen_US
dc.description.abstractWe report high resolution, rotationally resolved infrared spectra of the open shell van-der Waals complexes Br-HF, Cl-HF, and I-HF solvated in helium nanodroplets. Halogen atoms are formed by pyrolysis and embedded into the droplets, forming complexes with the HF. Experiments on highly reactive species of this type are well suited for study in helium droplets because of the inherent ultra low temperature environment. The ability to sequentially pick up and independently cool the dopant molecules plays a key role in limiting their reactivity. The observed spectra can be fit using a linear rotor Hamiltonian, in which the projection of the electronic angular momentum about the inter-nuclear axis is $|\Lambda| = 1$. The ground electronic states for these transitions are consistent with a $^{2}\Pi_{3/2}$ state.en_US
dc.format.extent183373 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleINFRARED SPECTROSCOPY OF THE OPEN SHELL VAN-DER WAALS COMPLEXES Br-HF, Cl-HF, AND I-HF SOLVATED IN SUPERFLUID HELIUM DROPLETSen_US
dc.typearticleen_US


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