Show simple item record

dc.creatorBlair, A. C.en_US
dc.creatorHaber, T.en_US
dc.creatorNesbitt, David J.en_US
dc.date.accessioned2006-06-15T20:34:17Z
dc.date.available2006-06-15T20:34:17Z
dc.date.issued2003en_US
dc.identifier2003-MF-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/20796
dc.description$^{a}$Y. Endo, S. Saito, E. Hirota, Can. J. Phys. 62, 1347 (1984)en_US
dc.descriptionAuthor Institution: JILA, University of Coloradoen_US
dc.description.abstractVelocity collimation in the slit supersonic discharge expansion results in a strong reduction in residual Doppler broadening, which makes possible resolution of spin-rotation fine structure in open shell radicals in the near infrared. By way of example, spin-rotation splittings in the vibrational ground and excited state have been observed in the ro-vibrational spectrum of the symmetric C-H-vibration $(3055.07723(63) cm^{-1})$of chloromethyl radical, for both K = 0 and 1 nuclear spin species. Rovibrational line shapes have been fitted to a spin-rotation Hamiltonian, including rotational-asymmetry splitting as well as hyperfine interactions. Spin-rotation coupling constants have been obtained for the vibrational excited state, with ground state values taken from microwave $spectra.^{a}$en_US
dc.format.extent159595 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSPIN-ROTATION INTERACTIONS IN CHLOROMETHYL RADICALen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record