Show simple item record

dc.creatorZehnacker, Anneen_US
dc.creatorBarbu, Leen_US
dc.creatorLahmani, F.en_US
dc.date.accessioned2006-06-15T20:12:29Z
dc.date.available2006-06-15T20:12:29Z
dc.date.issued2001en_US
dc.identifier2001-RF-13en_US
dc.identifier.urihttp://hdl.handle.net/1811/20153
dc.description$^{a}$M. Mons, F. Piuzzi, I. Dimicoli, A. Zehnacker, F. Lahmani. Phys. Chem. Chem. Phys. 2 5065 (2000). $^{b}$K. Le Barbu, V. Brenner, Ph. Millie, F. Lahmani, A. Zehnacker-Rentien, J. Phys. Chem. A 102 128 (1998).en_US
dc.descriptionAuthor Institution: Dept. of Chemistry, Laboratoire de Photophysique Moleculaire du CNRSen_US
dc.description.abstractChiral discrimination plays a key-role in life-chemistry and takes place through the formation of contact pairs implying short-range stereospecific interactions: spectroscopic measurements of jet-cooled van der Waals complexes of chiral molecules therefore provides a powerful strategy for addressing the question of chiral $recognition^{a}$. We present here a study of hydrogen-bonded complexes of chiral molecules by double resonance techniques, either UV/UV (hole burning $spectroscopy)^{b}$ or IR/UV fluorescence depletion spectra. Besides an spectroscopic means of discriminating between two enantiomers, the results presented here, coupled with DFT calculations, bring information on the nature of the forces responsible for chiral recognition. The role of the formation of a hydrogen-bonds network in chiral discrimination will be discussed.en_US
dc.format.extent213488 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleCHIRAL DISCRIMINATION IN JET-COOLED VAN DER WAALS COMPLEXES: ELECTRONIC AND VIBRATIONAL SPECTROSCOPYen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record