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dc.creatorOgilvie, J. F.en_US
dc.date.accessioned2006-06-15T20:08:10Z
dc.date.available2006-06-15T20:08:10Z
dc.date.issued2001en_US
dc.identifier2001-ME-01en_US
dc.identifier.urihttp://hdl.handle.net/1811/20030
dc.description$^{a}$J. F. Ogilvie, J. Oddershede and S. P. A. Sauer, Adv. Chem. Phys. 111, 475-535 (2000) $^{b}$J. F. Ogilvie, The Vibrational and Rotational Spectrometry of Diatomic Molecules [Academic Press, London U.K., 1998] $^{c}$J. K. G. Watson, J. Mol. Spectrosc. 80, 411-421 (1980)en_US
dc.descriptionAuthor Institution: Department of Chemical Engineering, Simon Fraser Universityen_US
dc.description.abstractAlthough long recognised by practitioners of experiments on molecular beams and microwave spectra, the importance of effects played by the rotational g factor in infrared and Raman spectra measured under conditions of great resolution tends to be neglected. Both experimental and computational methods to obtain values of this quantity are well $developed.^{a,b}$ Watson included within an expression for reduced mass a correction for net electric charge on a molecular $ion,^{c}$ but numerator and denominator of this expression are intrinsically inconsistent: the function of this correction is properly assigned to the rotational g factor of such ions. We discuss some examples of deduction of values of the rotational g factor from infrared spectra of diatomic and triatomic molecular compounds, and illustrate how these values can assist and improve reduction of frequencies and wave numbers of many spectral lines to few parameters in radial functions.en_US
dc.format.extent561498 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE ROTATIONAL g FACTOR IN ANALYSIS OF INFRARED AND RAMAN SPECTRA OF SMALL MOLECULES IN GASEOUS SAMPLESen_US
dc.typearticleen_US


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