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dc.creatorWang, W. F.en_US
dc.creatorSirota, J. Marcosen_US
dc.creatorReuter, D. C.en_US
dc.date.accessioned2006-06-15T19:24:49Z
dc.date.available2006-06-15T19:24:49Z
dc.date.issued1999en_US
dc.identifier1999-WH-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/19578
dc.descriptionAuthor Institution: Joint Center for Earth Systems Technology, University of Maryland Baltimore County; NASA Goddard Space Flight Center, Planetary Systems Branchen_US
dc.description.abstractPressure broadening coefficients have been measured in the $841 cm^{-1} \nu_{10}$ band of allene perturbed by nitrogen. The high-resolution absorption infrared spectra were recorded by a FTIR spectrometer at temperatures of 200, 250 and 300 K. The Voigt line shape, convoluted with the sinc instrument function, was used in the fit of the observed rovibrational lines. No regular J and K dependence of the broadening coefficients was observed for this strong symmetric-top-molecule band. The power-exponential-gap (PEG) fitting law and infinite-order-sudden (IOS) scaling law were effectively modified and employed for the fit of measured broadening coefficients. A selection rule of $|\Delta m| = 0$ was found to be necessary to optimize the simulation. For the modified IOS, the Coriolis resonance of $\nu_{10}$ with the nearby $\nu_{g}$ has been taken into account. For the 200K spectrum, more than 180 broadening coefficients for transitions up to $J^{\prime \prime} = 40$ and $K^{\prime \prime} = 8$ were reproduced to an accuracy of 14\% and 13\% by the PEG and IOS laws respectively. Results on the temperature dependence of the broadening coefficients for several spectral lines are also presented.en_US
dc.format.extent130449 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleFTIR MEASUREMENTS OF $N_{2}$-INDUCED PRESSURE BROADENING OF $ALLENE(C_{3}H_{4})$ IN THE $\nu_{10}$ BAND NEAR $840 cm^{-1}$en_US
dc.typearticleen_US


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