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dc.creatorLavrich, R. J.en_US
dc.creatorTubergen, Michael J.en_US
dc.date.accessioned2006-06-15T19:23:46Z
dc.date.available2006-06-15T19:23:46Z
dc.date.issued1999en_US
dc.identifier1999-WF-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/19548
dc.descriptionAuthor Institution: Department of Chemistry, Kent State Universityen_US
dc.description.abstractThe structure of the amino acid derivative alaninamide was determined by substitution of all the heavy atoms except oxygen. Assignment of the rotational spectrum of the 1:1 complex of alaninamide and water yielded rotational constants for the most abundant isotopomer: $A = 4789 (3) MHz, B = 1271.872 (8) MHz$, and $C = 1111.394(8)$ MHz. Preliminary data from two $^{15}N$ isotopomers indicate that the conformation of the alaninamide monomer is relatively unchanged upon complexation and that the water complex has a cyclic hydrogen bonded network, in which the water interacts with the carbonyl oxygen and an amide hydrogen.en_US
dc.format.extent82877 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleROTATIONAL SPECTRUM AND STRUCTURE OF A VAN DER WAALS COMPLEX BETWEEN AN AMINO ACID DERIVATIVE AND WATER: ALANINAMIDE - $H_{2}O$en_US
dc.typearticleen_US


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