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dc.creatorVan Wijngaarden, Jenniferen_US
dc.creatorJäger, Wolfgangen_US
dc.date.accessioned2006-06-15T19:17:54Z
dc.date.available2006-06-15T19:17:54Z
dc.date.issued1999en_US
dc.identifier1999-RG-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/19370
dc.descriptionAuthor Institution: Department of Chemistry, University of Albertaen_US
dc.description.abstractRotational spectra of the $Ne-NH_{3}$ and $Kr-NH_{3}$ van der Waals complexes were measured between 4 and 24 GHz using a pulsed jet cavity Fourier transform microwave spectrometer. The isotopomers studied include those of $^{14}NH_{3}$ and $^{15}NH_{3}$ with $^{22}$Ne and $^{20}Ne$ and with the 5 most abundant isotopes of Kr. Transitions corresponding to the $RG+NH_{3} \Sigma(J=0,|k|-0)$ internal rotor state have been measured and assigned for the Ne and Kr isotopomers and transitions related to the $\Sigma(j=1,|k|=1)$ state have been tentatively assigned for the Kr isotopomers. The spectra of the complexes containing $^{83}Kr$ and $^{14}N$ showed nuclear hyperfine structure due to the quadrupole moments of the nuclei. Rotational, centrifugal distortion and quadrupole coupling constants were determined and used to calculate structural parameters.en_US
dc.format.extent88508 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleROTATIONAL SPECTRA OF THE $Ne-NH_{3}$ and $Kr-NH_{3}$ VAN DER WAALS COMPLEXESen_US
dc.typearticleen_US


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