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dc.creatorDrouin, Brian J.en_US
dc.creatorKukolich, Stephen G.en_US
dc.date.accessioned2006-06-15T19:14:46Z
dc.date.available2006-06-15T19:14:46Z
dc.date.issued1999en_US
dc.identifier1999-MH-08en_US
dc.identifier.urihttp://hdl.handle.net/1811/19272
dc.descriptionAuthor Institution: Department of Chemistry, University of Arizonaen_US
dc.description.abstractMicrowave spectra of seven isotopomers of tetracarbonylethylenciron were recorded using Fourier transform microwave spectroscopy. Rotational transitions for $a{^{\prime}}c^{\prime}$ dipole moment were measured in the 4 - 12 GHz range. The moments of inertia of the seven isotopomers were used in a Kraitchman analysis, and also in two different least squares fitting analyses to determine the molecular structure of the compound. The ethylene ligand exhibits significant structural changes upon complexation to iron, primarily an increase in C-C bond length and movement of the hydrogen atoms away from the metal center.en_US
dc.format.extent70470 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleCOMPLETE STRUCTURE DETERMINATION OF ETHYLENEIRONTETRACARBONYL FROM THE ROTATIONAL SPECTRUMen_US
dc.typearticleen_US


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