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dc.creatorLichau, Holgeren_US
dc.creatorLock, Michaelen_US
dc.creatorWinnewisser, M.en_US
dc.creatorRoss, Stephen C.en_US
dc.date.accessioned2006-06-15T19:12:45Z
dc.date.available2006-06-15T19:12:45Z
dc.date.issued1999en_US
dc.identifier1999-FB-03en_US
dc.identifier.urihttp://hdl.handle.net/1811/19206
dc.description$^{a}$ H. Lichau, B.P. Winnewisser, M. Winnewisser, C.W. Gillies, and J.Z. Gillies, 53rd Int. Symposium, talk TH09 (1998) $^{b}$ K.M.T. Yamada, F.W. Birss, and M.R. Alien, J. Mol. Spectrosc. 112, 347-356 (1985)en_US
dc.descriptionAuthor Institution: Physikalisch-Chemisches Institut, Justus-Liebig-Universit\""{a}t; Department of Physics, University of New Brunswicken_US
dc.description.abstractThe band system of the low-lying CCN bending mode $\nu_{7}$ of the pseudohalofulminate NCCNO around $85 cm^{-1}$ has been recorded by high resolution FTIR spectroscopy to supplement our previous investigation of the pure rotational spectrum, which had revealed some slight, but significant indications of $quasilinearity^{a}$. Besides rovibrational transitions of the fundamental band, rovibrational transitions belonging to the first, second, third, and fourth hot band could be assigned. Using a conventional linear-molecule type $Hamiltonian^{b}$, these rovibrational transitions have been analyzed together with the pure rotational transitions. The results of this analysis confirm a moderate anharmonicity in the CCN bending potential. To quantify this anharmonicity, the combined data have been subjected to a semirigid bender analysis, which resulted in a rather flat bending potential with a significant quartic contribution.en_US
dc.format.extent121775 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE LOW-LYING CCN BENDING MODE OF THE CLOSE-TO-LINEAR MOLECULE NCCNOen_US
dc.typearticleen_US


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