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dc.creatorDavis, Scotten_US
dc.creatorUy, Daireneen_US
dc.creatorKable, Scott H.en_US
dc.creatorNesbitt, David J.en_US
dc.date.accessioned2006-06-15T19:11:38Z
dc.date.available2006-06-15T19:11:38Z
dc.date.issued1998en_US
dc.identifier1998-WH-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/19170
dc.descriptionAuthor Institution: JILA, National Institute of Standards and Technology and Department of Chemistry and Biochemistry, University of Colorado; JILA visiting fellow on leave from Division of Physical Chemistry, University of Sydney; JILA, National Institute of Standards and Technology and Department of Chemistry and Biochemistry, University of Coloradoen_US
dc.description.abstractThe $C_{3}H_{5}$ cyclopropyl radical has been generated in a slit supersonic discharge source and the infrared spectrum in the CH stretching region recorded via a direct absorption difference frequency spectrometer. The radical is generated by expanding a dilute (1\%) mix of cyclopropyl bromide in a diluent of Ne/He. Precursor and radical absorption are differentiated by simultaneous gated detection and gated discharge current. Transitions observed around $3118 cm^{-1}$ and $3041 cm^{-1}$ are tentatively assigned to the lone CH stretch and the asymmetric $CH_{2}$ stretchs, respectively. A more detailed rotational assignment is currently in progress and the results will be reported, providing both structural information and a detailed view into the inversion tunneling of the lone hydrogen through the radical center.en_US
dc.format.extent130372 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleHIGH RESOLUTION IR SPECTRA OF CYCLOPROPYL RADICALen_US
dc.typearticleen_US


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