dc.creator Davis, Scott en_US dc.creator Uy, Dairene en_US dc.creator Kable, Scott H. en_US dc.creator Nesbitt, David J. en_US dc.date.accessioned 2006-06-15T19:11:38Z dc.date.available 2006-06-15T19:11:38Z dc.date.issued 1998 en_US dc.identifier 1998-WH-07 en_US dc.identifier.uri http://hdl.handle.net/1811/19170 dc.description Author Institution: JILA, National Institute of Standards and Technology and Department of Chemistry and Biochemistry, University of Colorado; JILA visiting fellow on leave from Division of Physical Chemistry, University of Sydney; JILA, National Institute of Standards and Technology and Department of Chemistry and Biochemistry, University of Colorado en_US dc.description.abstract The $C_{3}H_{5}$ cyclopropyl radical has been generated in a slit supersonic discharge source and the infrared spectrum in the CH stretching region recorded via a direct absorption difference frequency spectrometer. The radical is generated by expanding a dilute (1\%) mix of cyclopropyl bromide in a diluent of Ne/He. Precursor and radical absorption are differentiated by simultaneous gated detection and gated discharge current. Transitions observed around $3118 cm^{-1}$ and $3041 cm^{-1}$ are tentatively assigned to the lone CH stretch and the asymmetric $CH_{2}$ stretchs, respectively. A more detailed rotational assignment is currently in progress and the results will be reported, providing both structural information and a detailed view into the inversion tunneling of the lone hydrogen through the radical center. en_US dc.format.extent 130372 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title HIGH RESOLUTION IR SPECTRA OF CYCLOPROPYL RADICAL en_US dc.type article en_US
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