RYDBERG STATES CONVERGING TO HIGHER VIBRATIONALLY EXCITED STATES OF $HCO^{+}$.
Publisher:
Ohio State UniversityAbstract:
Single rotational levels photoselected in the strongest bent $B^{2}A^{\prime}$ state of HCO serve as intermediate states in double resonance transitions to Rydberg states built on higher vibrationally excited levels of the linear $HCO^{+}$ core. Frank-Condon factors for the bent-to-linear transitions discriminate against resonances converging to lower lying vibrational states. Widths and intensities of multiple quantum vibrational autoionization resonances are affected by the level of core excitation.
Description:
Author Institution: Department of Chemistry, Purdue University
Type:
articleOther Identifiers:
1998-WG-07Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.