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dc.creatorDevi, V. Malathyen_US
dc.creatorBenner, D. Chrisen_US
dc.creatorSmith, M. A. H.en_US
dc.creatorRinsland, C. P.en_US
dc.creatorGuelachvili, G.en_US
dc.creatorBrown, L. R.en_US
dc.date.accessioned2006-06-15T19:10:51Z
dc.date.available2006-06-15T19:10:51Z
dc.date.issued1998en_US
dc.identifier1998-WF-11en_US
dc.identifier.urihttp://hdl.handle.net/1811/19143
dc.description$^{a}$ D. Chris Benner, C.P. Rinsland, V. Malathy Devi, M.A.H. Smith, and D. Atkins, JQSRT 53, 705-721 (1995). $^{b}$ L.S. Rothman et al., JQSRT 48, 469-507 (1992); L.S. Rothman et al., JQSRT, in press (1998).en_US
dc.descriptionAuthor Institution: Department of Physics, The College of William and Mary; Atmospheric Sciences Division, NASA Langley Research Center; Laboratoire de Physique Moleculaire et Applications (LPMA), CNRS,, Universite Paris-Sud; Jet Propulsion Laboratory, California Institute of Technologyen_US
dc.description.abstractSelf- and air-broadening and shift coefficients for numerous $CH_{4}$ transitions in the $3 \mu$m region have been determined through analysis of high-resolution absorption spectra recorded by two different Fourier transform spectrometer (FTS) systems. The first set of spectra was recorded using the 1-m FTS at the McMath-Pierce facility of the National Solar Observatory at Kitt Peak; resolution was $0.01 cm^{-1}$. This data set included both self-broadened $CH_{4}$ spectra with cell path lengths of 5,10,25,150, and 2500 cm and pressures ranging from 0.4 Torr to 456 Torr, and air-broadened spectra of $^{12}CH_{4}$ and $^{13}CH_{4}$ with cell path lengths of 5,25,50, and 150 cm and total pressures from about 100 Torr to 400 Torr. A second set of self-broadened $CH_{4}$ spectra was recorded at higher resolution $(0.0027 cm^{-1})$ using the FTS of the Laboratoire de Physique Moleculaire et Applications in Orsay. Path lengths for these spectra varied from 1.7 cm to 4 m, and pressures ranged from less than 1 Torr to over 500 Torr. A multispectrum nonlinear least-squares $procedure^{a}$ was used to fit over 40 spectra simultaneously to determine self- and air-broadening and shift coefficients for more than 500 lines; most of these are in the $\nu_{3}$ and $\nu_{2} + \nu_{4}$ bands. Differences between air- and self-broadening and shifts of $^{12}CH_{4}$ lines will be discussed, and air-broadening and shift coefficients for $^{12}CH_{4}$ and $^{13}CH_{4}$ will be compared. We will also compare our measurements with the values on the current HITRAN $compilation^{b}$ and with other available measurements.en_US
dc.format.extent190872 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleSELF- AND AIR-BROADENING AND SHIFT COEFFICIENTS OF $CH_{4}$ LINES IN THE $3 \mu$m REGIONen_US
dc.typearticleen_US


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