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dc.creatorMorgan, Meganen_US
dc.creatorBaumann, C. A.en_US
dc.date.accessioned2006-06-15T19:10:05Z
dc.date.available2006-06-15T19:10:05Z
dc.date.issued1998en_US
dc.identifier1998-TJ-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/19119
dc.description$^{a}$ J. Mason, J. Chem. Soc. 1963, 4531.en_US
dc.descriptionAuthor Institution: Titleist Foot Joy World Wide; Department of Chemistry, University of Scrantonen_US
dc.description.abstractWe report the results of laser photolysis ($\lambda = 670, 633 nm)$ of $CF_{3}NO$ trapped in solid argon, krypton, xenon, nitrogen and oxygen. Infrared spectroscopy was used to characterize the photoproducts and monitor the progress of the photolysis. In the gas phase photolysis, the parent molecule undergoes fragmentation upon $S_{1}$ excitation and the nascent fragments react with another monomer to produce the N-nitritoamine, $(CF_{3})_{2}NONO$, previously observed by $Mason^{a}$. Our condensed phase spectra indicate the formation of a different photoproduct, an azo or azoxy compound, with no apparent presence of the nitritoamine, and traces of $CF_{3}$ and NO in only the most dilute matrices. The quantum efficiency of this reaction exhibits a dependence on the matrix:reagent ratio. This concentration dependence is consistent with a second photolytic pathway where the $S_{1}$ monomer reacts with a ground state monomer in an adjacent matrix site before fragmentation can occur.en_US
dc.format.extent112589 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE PRODUCTION AND INFRARED SPECTRUM OF A PHOTODIMER OF TRIFLUORONITROSOMETHANE $(CF_{3}NO)$ ISOLATED IN INERT GAS MATRICESen_US
dc.typearticleen_US


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