dc.creator Storm, Volker en_US dc.creator Dreizler, H. en_US dc.creator Consalvo, Daniela en_US dc.date.accessioned 2006-06-15T19:05:59Z dc.date.available 2006-06-15T19:05:59Z dc.date.issued 1998 en_US dc.identifier 1998-RJ-10 en_US dc.identifier.uri http://hdl.handle.net/1811/18986 dc.description $^{a}$ D. Consalvo, V. Storm, and H. Dreizler, Chem. Phys. in press en_US dc.description Author Institution: Institut f\""{u}r Physikalische Chemie der CAU, Olshausenstr. 40-60; Institut f\""{u}r Physikalische Chemie der RWTH, Templergraben 59 en_US dc.description.abstract We recently presented the rotational spectra of aniline, $C_{6}H_{7}N$, complexed with $Ar, ^{20}Ne$ and $^{22}Ne^{a}$. Now we will describe the analysis of two additional isotopomer spectra of the $^{15}N$-substituted aniline complexed with Ar and Ne. The very accurate values of the rotational constants for both the parent molecular cluster and its derivatives, obtained using a Fourier transform microwave spectrometer in the spectral region 1-18 GHz, now confirm that there is one structure compatible with the full set of moments of inertia obtained. Due to large amplitude motions exhibited by rare gas atoms in weakly bounded van der Waals systems, it raises the question about the meaning of the rare gas coordinates obtained from such a study. Hopefully, a global, analysis of microwave and available UV results, supported by quantum calculations, will extract more information on the cluster structure and dynamics. en_US dc.format.extent 119308 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title DO WE REALLY KNOW THE STRUCTURE OF ANILINE-X $(X=AR, NE)$ IN THE GROUND ELECTRONIC STATE $S_{0}$? en_US dc.type article en_US
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