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dc.creatorWhitham, C. J.en_US
dc.creatorBrown, J. M.en_US
dc.creatorBeaton, S. A.en_US
dc.creatorIto, Y.en_US
dc.descriptionAuthor Institution: The Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford; Department of Chemistry, The University of British Columbia; Department of Mechanical Engineering, Nagaoka University of Technologyen_US
dc.description.abstractThe $\tilde{B}=\tilde{X}$ transition of $CaOCH_{3}$ has been observed at Doppler limited resolution and rotationally analysed. The molecule was generated using a laser ablation/molecular beam source in which a solid calcium rod was ablated and a mixture of argon seeded with a few percent of methanol was used as the carrier gas. The rotational analysis of the band is consistent with a linear Ca-O-C geometry in both electronic states and hence $C_{3x}$ symmetry for the $CaOCH_{3}$ radical. The values of the spin-rotation parameters determined for the excited $\tilde{B}^{1}A_{1}$ state will be discussed.en_US
dc.format.extent85375 bytes
dc.publisherOhio State Universityen_US
dc.titleLASER EXCITATION SPECTROSCOPY OF THE $\tilde{B}^{2}A_{1}-\tilde{X}^{2}A_{1}$ TRANSITION OF $CaOCH_{3}$en_US

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