Show simple item record

dc.creatorSchnupf, U.en_US
dc.creatorBasinger, W. H.en_US
dc.creatorHeaven, M. C.en_US
dc.date.accessioned2006-06-15T18:58:18Z
dc.date.available2006-06-15T18:58:18Z
dc.date.issued1993en_US
dc.identifier1993-WH-6en_US
dc.identifier.urihttp://hdl.handle.net/1811/18732
dc.descriptionAuthor Institution: Department of Chemistry, Emory Universityen_US
dc.description.abstractCH/D-Ne complexes were generated in a free-jet expansion, and detected by laser excitation of bands associated with the $CH/D A^{2} \Delta-X^{2} \Pi$ and $B^{2}\Sigma-X^{2}\Pi$ transitions. The monomer B-X 0-0 and 1-0 transitions were each accompanied by four strong features of the complex. Rotational analysis of the origin band yielded rotational constants of (CH-Ne) $B^{\prime}=0.117$ and $B^{\prime \prime}=0.149 cm^{-1}$. Hence the van der Waals bond lengthens on excitation to the B state. Two strong complex features were seen in conjunction with the monomer $A-X 0-0$ transition. The rotational structures of these features were much more congested than those of the $B-X$ bands. A preliminary analysis yields an A state rotational constant which is slightly larger than that of the ground state, implying that the intermolecular bond shortens on excitation to the A state. Results from detailed analyses of the $A-X$ and $B-X$ systems will be presented.en_US
dc.format.extent71383 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleROTATIONALLY-RESOLVED ELECTRONIC SPECTRA FOR THE CH-Ne and CD-Ne VAN DER WAALS COMPLEXESen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record