dc.creator Tubergen, Michael J. en_US dc.creator Kuczkowski, R. L. en_US dc.date.accessioned 2006-06-15T18:54:17Z dc.date.available 2006-06-15T18:54:17Z dc.date.issued 1993 en_US dc.identifier 1993-TC-2 en_US dc.identifier.uri http://hdl.handle.net/1811/18610 dc.description Author Institution: Department of Chemistry, University of Michigan en_US dc.description.abstract A microwave spectrum of the trimethylamine-water complex consisting of six transitions has been observed using a Fourier-transform microwave spectrometer. A symmetric top spectrum has been observed with $B_{0} = 2508.640(1)$ MHz. Using a diatomic approximation, the center-of-mass separation is estimated to be 3.8 {\AA}. The nuclear quadrupole hyperfine structure arising from the $^{14}N$ nucleus was assigned and fit to $X_{aa} = -5.015 (3)$ MHz. The second order Stark splittings of the $3_{0}-2_{0}$ transition of the $^{15}N$ isotopomer were used to calculate $\mu = 2.37 (1)$ D. Symmetric top spectra of the $D_{2}O$ and HDO complexes with both $^{14}N-$ and $^{15}N$-trimethylamine have also been observed. en_US dc.format.extent 65025 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE MICROWAVE SPECTRUM AND STRUCTURE OF THE TRIMETHYLAMINE-WATER COMPLEX en_US dc.type article en_US
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