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dc.creatorWang, B.en_US
dc.creatorTam, C. N.en_US
dc.creatorKeiderling, T. A.en_US
dc.date.accessioned2006-06-15T18:53:09Z
dc.date.available2006-06-15T18:53:09Z
dc.date.issued1993en_US
dc.identifier1993-RH-4en_US
dc.identifier.urihttp://hdl.handle.net/1811/18576
dc.descriptionAuthor Institution: Department of Chemistry, University of Illinois at Chicagoen_US
dc.description.abstractThe magnetic vibrational circular dichroism (MVCD) spectra of the E-symmetry, $\nu_{4}$ mode of $HCCl_{3}, HCBr_{3}$, and $DCCl_{3}$ are presented. In each case, an MVCD A-term indicating a first order vibrational Zeeman effect is observed. The vibrational g-values for the $\nu_{4}$ mode of these haloforms were determined for the first time by moment analysis of the MVCD and absorption spectra. The fact that similar MVCD intensity is found for both gas and solution phase $HCCl_{3}$ and $HCBr_{3}$ indicates that there is little contribution from the Coriolis coupling, which is generally the major contributor to the vibrational Zeeman effect. A partially charged ``elastic bar'' model is used to qualitatively explain the observed MVCD A-terms.en_US
dc.format.extent70654 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleVIBRATIONAL ZEEMAN EFFECT FOR THE $\nu_{4}$ MODE OF HALOFORMS $(HCX_{3}$) AS DETERMINED BY MVCDen_US
dc.typearticleen_US


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