dc.creator Wang, B. en_US dc.creator Tam, C. N. en_US dc.creator Keiderling, T. A. en_US dc.date.accessioned 2006-06-15T18:53:09Z dc.date.available 2006-06-15T18:53:09Z dc.date.issued 1993 en_US dc.identifier 1993-RH-4 en_US dc.identifier.uri http://hdl.handle.net/1811/18576 dc.description Author Institution: Department of Chemistry, University of Illinois at Chicago en_US dc.description.abstract The magnetic vibrational circular dichroism (MVCD) spectra of the E-symmetry, $\nu_{4}$ mode of $HCCl_{3}, HCBr_{3}$, and $DCCl_{3}$ are presented. In each case, an MVCD A-term indicating a first order vibrational Zeeman effect is observed. The vibrational g-values for the $\nu_{4}$ mode of these haloforms were determined for the first time by moment analysis of the MVCD and absorption spectra. The fact that similar MVCD intensity is found for both gas and solution phase $HCCl_{3}$ and $HCBr_{3}$ indicates that there is little contribution from the Coriolis coupling, which is generally the major contributor to the vibrational Zeeman effect. A partially charged elastic bar'' model is used to qualitatively explain the observed MVCD A-terms. en_US dc.format.extent 70654 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title VIBRATIONAL ZEEMAN EFFECT FOR THE $\nu_{4}$ MODE OF HALOFORMS $(HCX_{3}$) AS DETERMINED BY MVCD en_US dc.type article en_US
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