dc.creator Chang, Bor-Chen en_US dc.creator Williamson, James M. en_US dc.creator Miller, Terry A. en_US dc.date.accessioned 2006-06-15T18:52:05Z dc.date.available 2006-06-15T18:52:05Z dc.date.issued 1993 en_US dc.identifier 1993-RE-7 en_US dc.identifier.uri http://hdl.handle.net/1811/18544 dc.description $^{1.}$ Chang et al., J. Ogem. Phys. 95, 7086 (1991). $^{2.}$ Chang et al., J. Chem. Phys. 97, 7999 (1992). en_US dc.description Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University en_US dc.description.abstract The rotational, fine, and hyperfine structure in the high resolution electronic spectra of the $Ar \cdot OH/D \bar{A} \leftarrow \bar{X}$ bands has been well studied and $reported.^{1.2}$ A comparison between these results and our recent analyses on the spectra of $Ne \cdot OH/D$ reveals even more interesting information about the nature of these open-shell complexes. It is found that there are similarities and differences in the spectra of $Ne \cdot OH/D$ and $Ar\cdot OH/D$. Both Ar and Ne complexes have bands which can be characterized by transitions from the ground vibrational level in the $\bar{X}$ state to the $\bar{A}$ state levels either with or without a quantum in torsional (bending) mode. The bands of both Ar and Ne complexes, involving no quanta in the $\bar{A}$ state bending mode, show similar rotation, fine, and hyperfine structure. On the other hand, those bands involving bend excitation in the $\bar{A}$ state of $Ne \cdot OH/D$ show quite distinct differences to those of $Ar \cdot OH/D$. We have completed analyses on all observed spectra or Ar and Ne complexes. A detailed comparison on rotational, fine, and hyperfine structure as well as their physical interpretations will be discussed. en_US dc.format.extent 80341 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title HIGH RESOLUTION ELECTRONIC SPECTROSCOPY OF $Ar \cdot OH$ AND $Ne \cdot OH$ en_US dc.type article en_US
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