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dc.creatorYu, L. C.en_US
dc.creatorFrancis, A. H.en_US
dc.date.accessioned2006-06-15T18:41:29Z
dc.date.available2006-06-15T18:41:29Z
dc.date.issued1990en_US
dc.identifier1990-RG-12en_US
dc.identifier.urihttp://hdl.handle.net/1811/18214
dc.descriptionAuthor Institution: Department of Chemistry, University of Michiganen_US
dc.description.abstract$Pbl_{2}$ exhibits a lamellar $Cdl_{2}$ crystal structure, similar to that of the transition metal ditchalcogerudes $(MX_{2})$ and transition metal phosphorus trichalcogenides $(MPX_{3})$. When $Pbl_{2}$ is exposed to any of a variety of organic Lewis bases. it undergoes a solid-state reaction that produces a material with a substantially altered electronic spectrum. Because the reaction is similar to the intercalation reactions of the lamellar chalcogenide lattices with Lewis bases, the reaction of $Pbl_{2}$ has also been described as an intercalation reaction. Examination of the liquid helium temperature photo-excitation and photo-luminescence spectra of the reaction product with pyridine suggests that there are important differences between the reaction products of the lamellar chalcogenide lattices and $Pbl_{2}$ with organic Lewis bases. The latter may be described better as coordination compounds resulting from a reversible, heterogeneous reaction between solid $Pbl_{2}$ and the vapor or liquid phase of the organic liganden_US
dc.format.extent55275 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titlePHOTO-EXCITATION AND PHOTOLUMINESCENCE STUDY OF COORDINATION COMPLEXES OF LEAD DHODIDE WITH PYRIDINEen_US
dc.typearticleen_US


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