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dc.creatorJacox, Marilyn E.en_US
dc.date.accessioned2006-06-15T18:09:21Z
dc.date.available2006-06-15T18:09:21Z
dc.date.issued1988en_US
dc.identifier1988-MH-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/17517
dc.description$^{1}$ D. E. Milligan and M. E. Jacox, J. Chem, Phys, 54, 927 (1971).en_US
dc.descriptionAuthor Institution: Molecular Spectroscopy Division, National Bureau of Standardsen_US
dc.description.abstractThe OH stretching, in-plane OH deformation, and torsional fundamentals of t-HOCO, previously reported1 in a study of the vacuum-ultraviolet photolysis of $H_{2}O$ in a CO matrix, experience large shifts upon removal of the hydrogen-bonding perturbation by isolation of t-HOCO in solid argon. Because of these large shifts, a Fermi resonance perturbation of the $C=O$ stretching fundamental is altered, resulting in a substantial matrix dependence for the isotopic shift in this fundamental of t-DOCO. t-HOCO affords an unusual opportunity to study the effect of hydrogen bonding at either end of the molecule. Infrared spectral data for $OC\ldots H-O-C=O$, isolated t-HOCO, and $H-O-C=O\ldots HF$ will be compared.en_US
dc.format.extent107243 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleTHE EFFECT OF HYDROGEN BONDING ON THE VIBRATIONAL SPECTRUM OF t-HOCO TRAPPED IN SOLID Ar AND COen_US
dc.typearticleen_US


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