dc.creator Sears, Trevor J. en_US dc.date.accessioned 2006-06-15T17:49:14Z dc.date.available 2006-06-15T17:49:14Z dc.date.issued 1986 en_US dc.identifier 1986-FA-9 en_US dc.identifier.uri http://hdl.handle.net/1811/16891 dc.description Address of Sears: Department of Chemistry, Brookhaven National Laboratory, Upton, NY 11973. en_US dc.description Author Institution: en_US dc.description.abstract The $\nu_{2}$, bending, fundamental band of $CO_{2}^{+}$ has been detected by diode laser absorption spectroscopy at wavelengths between $17.5 \mu m$ and $22.2 \mu m$. The combined effects of vibronic and spin orbit coupling split the spectrum into several well separated component bands and information on all of the vibronic components associated with $v_{2} = 0$ and 1 has been obtained. Analysis of the spectra has yielded precise estimates of the rotational, A-doubling and spin uncoupling parameters while the vibronic splittings give information on the spin orbit coupling and the vibronic potential functions. $^{\ast}$Research carried out at Brookhaven National Laboratory was performed under contract DE-AC02-76CH00016 with the U. S. Department of Energy and supported by its Division of Chemical Sciences. en_US dc.format.extent 117560 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title INFRARED SPECTRUM OF THE RENNER-TELLER ACTIVE $\nu_{2}$ BAND of $X^{2}\Pi_{g}CO_{2}^{+\ast}$ en_US dc.type article en_US
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