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dc.creatorSrdanov, Vojislav I.en_US
dc.creatorHarris, David O.en_US
dc.date.accessioned2006-06-15T17:46:03Z
dc.date.available2006-06-15T17:46:03Z
dc.date.issued1984en_US
dc.identifier1984-TC-7en_US
dc.identifier.urihttp://hdl.handle.net/1811/16787
dc.description$^{1}$ B. Rosen, Nature, Lond., 156, 570 (1945).en_US
dc.descriptionAuthor Institution: Quantum Institute and the Department of Chemistry, University of Californiaen_US
dc.description.abstractLaser-induced fluorescence of NiO formed by the reaction of sputtered Ni atoms from a hollow cathode source with oxygen or ozone was studied. Some of the bands belonging to the Rosen's System $IV^{1}$ were vibrationally and rotationally analyzed. A new vibrational assignment is proposed. The rotational structure of the strongest band at 5176.5 {\AA} resembles $^{1}\Pi-^{1}\Pi$ or $\Omega^{\prime}=1$ to $\Omega^{\prime \prime}=1$ transition. Interesting features include a rotational perturbation in the excited state and extremely strong $\Omega$-doubling in the lower state. This suggests the presence of nearly degenerate $\Omega=0$ electronic state which could be another component of a $a^{3}\Sigma^{-}$ state in Hund's coupling case c. Preliminary rotational analysis of the 5176.5 {\AA} band gives $r^{\prime} = 1.73$ {\AA} and $r^{\prime \prime}_{v} = 1.62$ {\AA} for the equilibrium distances in the upper and lower electronic states.en_US
dc.format.extent668692 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleLASER SPECTROSCOPY OF NiO: ROTATIONAL ANALYSIS OF THE SYSTEM IV IN THE 5170 - 5500 {AA} REGIONen_US
dc.typearticleen_US


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