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dc.creatorThomas, R. Dykeen_US
dc.creatorMuenter, J. S.en_US
dc.date.accessioned2006-06-15T17:11:58Z
dc.date.available2006-06-15T17:11:58Z
dc.date.issued1974en_US
dc.identifier1974-RB-3en_US
dc.identifier.urihttp://hdl.handle.net/1811/16320
dc.descriptionAuthor Institution: Department of Chemistry, University of Rochesteren_US
dc.description.abstractAs reported last year, molecular beam electric resonance spectroscopy has been used to observe radio frequency and microwave transitions in water dimer produced in supersonic nozzle beam sources. Both $(H_{2}O)_{2}$ and $(D_{2}O)_{2}$ have been studied. Sufficient data have been obtained to provide the following structural parameters: the oxygen-oxygen internuclear distance is 2.98 $\pm$ 0.04 {\AA}, the hydrogen bond is linear to within $10^{\circ}$, and the hydrogen accepting molecule is oriented $50^{\circ} \pm 10^{\circ}$ from the hydrogen bond axis. Very large amplitude vibrations are clearly evident, but all data is consistent with an equilibrium structure having a plane of symmetry.The A component of the electric dipole moment has been measured for two vibrational states in the J = 2, K = 2 and J – 3, K = 3 states yielding$u_{22} = 2,5896(7) D, u33 = 2.5658(11) D$ and $\mu_{22} = 2.6350(11)$ D, and $\mu_{33} = 2.6238(8)$ D.en_US
dc.format.extent174187 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMOLECULAR STRUCTURE OF HYDROGEN BONDED WATER DIMERen_US
dc.typearticleen_US


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