dc.creator Hallin, K.- E. J. en_US dc.creator Jungen, Ch. en_US dc.creator Malm, D. N. en_US dc.creator Merer, A. J. en_US dc.date.accessioned 2006-06-15T17:09:39Z dc.date.available 2006-06-15T17:09:39Z dc.date.issued 1974 en_US dc.identifier 1974-FB-4 en_US dc.identifier.uri http://hdl.handle.net/1811/16230 dc.description Author Institution: Department of Chemistry, University of British Columbia; Laboratoire de Photophysique, Mol\'{e}culaire, B\^{a}timent 213, Facult\'{e} des Sciences, Universit\'{e} Paris-Sud; Department of Chemistry, University of British Columbia,n en_US dc.description.abstract Large numbers of ‘hot’ bands in the first electronic absorption system of $CS_{2}$ have been photographed at high resolution. Their rotational analysis has given accurate vibrational, rotational and $\ell$-type doubling constants for the higher overtones of the bending vibrations of $^{12}CS_{2}$ and $^{13}CS_{2}$- For $^{13}CS_{2}$ the data cover those levels with $v_{2}\leq 4, \ell \leq 2$, but for $^{12}CS_{2}$ where 40 m-atm absorbing path was attained, the data extend to levels with $v_{2} \leq 6, \ell \leq 3$. The great strength of these `hot’ bands results from the change of S-C-S bond angle in the transition, (which is $^{3}A_{2}(^{3}\Delta_{u}) – ^{-1} \Sigma_{g}^{+})$, and from the angle-dependence of the transition moment. en_US dc.format.extent 171105 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title HIGHER BENDING VIBRATIONAL LEVELS OF THE GROUND STATES OF $^{12}CS_{2}$ AND $^{13}CS_{2}$ en_US dc.type article en_US
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