THE VIBRATIONAL SPECTRA OF cis- AND trans-1,2- DIMETHOXYETHYLENE

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1973

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Ohio State University

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Abstract

The infrared and Raman spectra of cis- and trans-1,2-dimethoxyethylene have been determined. Band assignments of the stretching frequencies and some of the bending frequencies have been made and will be discussed. The double-bond stretching frequency of the cis-olefin ($1693 cm^{-1}$) is higher than that for the trans-material ($1661 cm^{-1}$). This is consistent with the greater stability of the cis-isomer.

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Author Institution: Chemistry Division Newark College of Engineering

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