Show simple item record

dc.creatorGillies, C. W.en_US
dc.creatorLattimer, Robert P.en_US
dc.creatorKuczkowski, R. L.en_US
dc.date.accessioned2006-06-15T17:05:52Z
dc.date.available2006-06-15T17:05:52Z
dc.date.issued1973en_US
dc.identifier1973-P-05en_US
dc.identifier.urihttp://hdl.handle.net/1811/16082
dc.descriptionAuthor Institution: Department of Chemistry, University of Michiganen_US
dc.description.abstractIn the ozonolysis of mixtures of ethylene and oxygen-18 formaldehyde, at least 90\% of the aldehydic oxygen that incorporated in the ozonide ring was found at the epoxide site (JACS 94, 7609 (1972). In order to set a more precise upper limit for this incorporation and to ascertain if any oxygen-18 was incorporated at the peroxide site, the microwave spectra of several oxygen-18 sepecies of ethylene ozonide have been assigned. These species were prepared by ozonizing ethylene with oxygen-18 ozone. These assignments together with similar assignments for propylene ozonide were then used to determine the site of aldehydic oxygen incorporation. The reactions studied include the ozonolysis of: 1) ethylene and formaldehyde; 2) ethylene and acetaldehyde; 3) propylene and formaldehyde; 4) propylene and acetaldehyde; 5) 2-butene and formaldehyde. The results of this study are related to several mechanistic proposals for the ozonolysis reaction.en_US
dc.format.extent190819 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleMICROWAVE SPECTRA OF OXYGEN-18 ETHYLENE AND PROPYLENE OZONIDE: OXYGEN-18 ALDEHYDE INSERTION OF THE OZONOLYSIS REACTIONen_US
dc.typearticleen_US


Files in this item

Thumbnail

Items in Knowledge Bank are protected by copyright, with all rights reserved, unless otherwise indicated.

This item appears in the following Collection(s)

Show simple item record