dc.creator Andrews, Lester en_US dc.creator Spiker, Robert C. en_US dc.date.accessioned 2006-06-15T17:03:58Z dc.date.available 2006-06-15T17:03:58Z dc.date.issued 1973 en_US dc.identifier 1973-H-07 en_US dc.identifier.uri http://hdl.handle.net/1811/16009 dc.description Author Institution: Department of Chemistry, University of Virginia, en_US dc.description.abstract Beams of alkali metal atoms and ozone molecules at high dilution in argon were condensed on a tilted copper wedge at $16^{0}K$ and examined by argon plasma laser excitation. Very intense bands red shifted near $1010 cm^{-1}$ showed small alkali metal effects and appropriate oxygen-18 shifts for assignment to the $\nu_{1}$ symmetric oxygen-oxygen mode of the ozonide ion in the $M^{+}O_{3}^{-}$ species. The intense fundamental and a regular progression of overtones out to $4\nu_{1}$ suggest that these spectra are probably due to the resonance Raman effect. Vibrational analysis for six isotopic ozonide species produced the oxygen-oxygen force constant $4.18 \pm 0.11 mdyn/{\AA}$. The spectroscopic value for the heat of atomization of the ozonide ion calculated from the vibrational constants $\omega_{1} = 1028.2$ $cm^{-1}$ and $X_{11} = 4.95$ $cm^{-1}$ for $Cs^{+}O_{3}$ is 153 kcal/mole, which agrees well with the thermodynamic value. en_US dc.format.extent 165800 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title RESONANCE RAMAN SPECTRUM AND VIBRATIONAL ANALYSIS OF THE OZONIDE ION IN THE ARCON MATRIX-ISOLATED $M^{+}O_{3}^{-}$ SPECIES en_US dc.type article en_US
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