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dc.creatorAndrews, Lesteren_US
dc.creatorSpiker, Robert C.en_US
dc.date.accessioned2006-06-15T17:03:58Z
dc.date.available2006-06-15T17:03:58Z
dc.date.issued1973en_US
dc.identifier1973-H-07en_US
dc.identifier.urihttp://hdl.handle.net/1811/16009
dc.descriptionAuthor Institution: Department of Chemistry, University of Virginia,en_US
dc.description.abstractBeams of alkali metal atoms and ozone molecules at high dilution in argon were condensed on a tilted copper wedge at $16^{0}K$ and examined by argon plasma laser excitation. Very intense bands red shifted near $1010 cm^{-1}$ showed small alkali metal effects and appropriate oxygen-18 shifts for assignment to the $\nu_{1}$ symmetric oxygen-oxygen mode of the ozonide ion in the $M^{+}O_{3}^{-}$ species. The intense fundamental and a regular progression of overtones out to $4\nu_{1}$ suggest that these spectra are probably due to the resonance Raman effect. Vibrational analysis for six isotopic ozonide species produced the oxygen-oxygen force constant $4.18 \pm 0.11 mdyn/{\AA}$. The spectroscopic value for the heat of atomization of the ozonide ion calculated from the vibrational constants $\omega_{1} = 1028.2$ $cm^{-1}$ and $X_{11} = 4.95$ $cm^{-1}$ for $Cs^{+}O_{3}$ is 153 kcal/mole, which agrees well with the thermodynamic value.en_US
dc.format.extent165800 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleRESONANCE RAMAN SPECTRUM AND VIBRATIONAL ANALYSIS OF THE OZONIDE ION IN THE ARCON MATRIX-ISOLATED $M^{+}O_{3}^{-}$ SPECIESen_US
dc.typearticleen_US


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