dc.creator Austin, Jared A. en_US dc.creator Churg, Antonie en_US dc.creator Levy, Donald H. en_US dc.date.accessioned 2006-06-15T17:03:29Z dc.date.available 2006-06-15T17:03:29Z dc.date.issued 1973 en_US dc.identifier 1973-F-10 en_US dc.identifier.uri http://hdl.handle.net/1811/15992 dc.description Author Institution: Department of Chemistry, The James Franck Institute en_US dc.description.abstract The microwave and magnetic resonance spectra of excited vibrational states of the OH radical have been observed in a cavity microwave spectrometer. The v = 0 - 4 vibrational levels have been observed in the reaction of hydrogen atoms with $F_{2}O$ and the v = 0 - 6 levels have been observed in the reaction of hydrogen atoms with ozone. The $^{2}\Pi_{1/2} (J = 3/2)$ and $^{2}\Pi_{3/2} (J = 3/2, 5/2,$ and $7/2)$. A-doubling transitions have been observed at either zero or high magnetic field. The variation of hyperfine, rotational, and A-doubling constants with vibrational level have been extracted from the observed spectrum. There is some evidence that the A-doubling is caused primarily by mixing of the $A^{2} \Sigma^{+}$ electronic state with the ground state. en_US dc.format.extent 162380 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE MICROWAVE AND MAGNETIC RESONANCE SPECTRA OF VIBRATIONALLY EXCITED OH RADICALS en_US dc.type article en_US
﻿