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dc.creatorWieser, H.en_US
dc.creatorDuckett, J. A.en_US
dc.creatorKydd, R. A.en_US
dc.date.accessioned2006-06-15T17:02:21Z
dc.date.available2006-06-15T17:02:21Z
dc.date.issued1973en_US
dc.identifier1973-D-10en_US
dc.identifier.urihttp://hdl.handle.net/1811/15949
dc.descriptionAuthor Institution: Department of Chemistry, The University of Calgary Calgary, Albertaen_US
dc.description.abstractThe far-infrared spectra of several deuterated analogues of trimethylene sulfide $(\alpha-d_{2},\beta-d_{2},\alpha,\alpha ^{\prime} - d_{4}$ and $d_{6}) $ have been measured in the vapor phase, all showing the usual sequence of Q-branches arising from transitions between ring puckering energy states. The isotopic dependence of the double minimum potential function governing the out-of-plane motion will be discussed briefly. Several combination band progressions resulting from ring puckering-vibrational interactions, notably in the $CH_{2}$ scissoring region, are reported. It is found that for some vibrationally excited states the puckering potential function does change appreciably from its form in the ground state.en_US
dc.format.extent148458 bytes
dc.format.mimetypeimage/jpeg
dc.language.isoEnglishen_US
dc.publisherOhio State Universityen_US
dc.titleT2N IN4. EVIDENCE OF RING PUCKERING IN DEUTERATED ANALOGUES OF TRIMETHYLENE SULFIDEen_US
dc.typearticleen_US


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