dc.creator Elzaro, R. A. en_US dc.date.accessioned 2006-06-15T17:01:57Z dc.date.available 2006-06-15T17:01:57Z dc.date.issued 1973 en_US dc.identifier 1973-CC-06 en_US dc.identifier.uri http://hdl.handle.net/1811/15934 dc.description Author Institution: Department of Chemistry, Michigan State University East Lansing en_US dc.description.abstract Microwave rotational spectra have been assigned for the ground vibrational state of the species of N-methylformamide in which the methyl group is cis to the oxygen atom. No spectra belonging to any other species have been identified. The transitions in the cis species are widely split into doublets and we have attributed the splitting to internal rotation of the methyl group. A least squares fit of 12 transitions gave the following parameters:$A_{0} = 19.4843$ GHz, $B_{0} = 6.3301$ GHz, $C_{0} = 4.9048$ GHz, $I_{\alpha} = 3.04$ u $\AA^{2}, \theta_{a\alpha} = 50.13^{\circ}$, and $V_{3} = 205$ cal/mole. The dipole moment, as determined from the Stark effect, is $3.86 \pm 0.02 D$. en_US dc.format.extent 125643 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title MICROWAVE SPECTRUM OF N-METHYLFORMAMIDE en_US dc.type article en_US
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